AY Honors/Rocks & Minerals - Advanced/Answer Key

3. Know two minerals that belong to each of the following crystal systems:

a. Isometric

A crystal of Sodium Chloride (common table salt)

The isometric crystal system (or cubic) is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in metallic crystals. Isometric crystals include

1. Sodium Chloride (NaCl, common table salt)
2. Gallium arsenide (GaAs) is a compound of two elements, Gallium and Arsenic. It is an important semiconductor and is used to make devices such as microwave frequency integrated circuits.
3. Zirconium dioxide (ZrO₂), sometimes known as zirconia, is a white crystalline oxide of zirconium. Single crystals of the cubic phase of zirconia are commonly used as a substitute for diamond in jewelry. Like diamond, cubic zirconia has a cubic crystal structure and a high index of refraction. Discerning a good quality cubic zirconia gem from a diamond is difficult, and most jewellers will have a thermal conductivity tester to identify cubic zircona by its low thermal conductivity (diamond is a very good thermal conductor).
4. Lead(II) nitrate is a chemical compound, the inorganic salt of nitric acid and lead, with the formula Pb(NO₃)₂. It is a colorless crystal or white powder and a strong, stable oxidizer.
5. Copper(I) oxide or cuprous oxide (Cu₂O) is an oxide of copper.

b. Hexagonal

Hexagonal crystal

In crystallography, the hexagonal crystal system is one of the 7 lattice point groups (see Hexagonal_lattice). It has the same symmetry as a right prism with a hexagonal base. Hexagonal crystals include:

1. Graphite, a form of pure carbon, used as a lubricant and as pencil lead.
2. Apatite is one of few minerals that are produced and used by biological micro-environmental systems. Hydroxylapatite is the major component of tooth enamel.
3. Quartz is the second most common mineral in the Earth's continental crust. It is made up of a lattice of silica (SiO₂) tetrahedra.
4. Beryl is a gemstone with the chemical formula Be₃Al₂(SiO₃)₆. The hexagonal crystals of beryl may be very small or range to several meters in size.

c. Tetragonal

Tetragonal cyrstal

Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a square base (a by a) and height (c, which is different from a). Tetragonal crystals include:

1. Wulfenite is a lead molybdate mineral with the formula PbMoO₄. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore".
2. Urea is an organic compound of carbon, nitrogen, oxygen and hydrogen, with the formula (NH₂)₂CO. It was the first organic compound to be artificially synthesized from inorganic starting materials.
3. Zircon is a mineral belonging to the group of nesosilicates. Its chemical name is zirconium silicate and its corresponding chemical formula is ZrSiO₄.

4. Know Mohs' scale of hardness and the simplified field tests of hardness. By using these field tests, collect a scale range of specimens from your own region to form your own hardness test set.

The Mohs scale of mineral hardness characterizes the scratch resistance of various minerals through the ability of a harder material to scratch a softer material. It was created in 1812 by the German mineralogist Friedrich Mohs and is one of several definitions of hardness in materials science.

Mohs based the scale on ten minerals that are all readily available. As the hardest known naturally occurring substance, diamond is at the top of the scale. The hardness of a material is measured against the scale by finding the hardest material that the given material can scratch, and/or the softest material that can scratch the given material. For example, if some material is scratched by apatite but not by fluorite, its hardness on the Mohs scale is 4.5.

The Mohs scale is a purely ordinal scale. For example, corundum (9) is twice as hard as topaz (8), but diamond (10) almost four times as hard as corundum. The table below shows comparison with absolute hardness measured by a sclerometer.

Hardness	Mineral	Absolute Hardness
1	Talc (Mg3Si4O10(OH)2)	1
2	Gypsum (CaSO4·2H2O)	2
3	Calcite (CaCO3)	9
4	Fluorite (CaF2)	21
5	Apatite (Ca5(PO4)3(OH-,Cl-,F-))	48
6	Orthoclase Feldspar (KAlSi3O8)	72
7	Quartz (SiO2)	100
8	Topaz (Al2SiO4(OH-,F-)2)	200
9	Corundum (Al2O3)	400
10	Diamond (C)	1500

An improvised hardness scale can be improvised in the field by using things a mineral enthusiast is likely to have on hand. On the Mohs scale, fingernail has hardness 2.5; copper penny, about 3.5; a knife blade, 5.5; window glass, 6.5; steel file, 6.5. Using these ordinary materials of known hardness can be a simple way to approximate the position of a mineral on the scale.

Hardness	Mineral
2.5	Fingernail
3.5	Copper penny
5.5	Knife blade
6.5	Window glass or steel file

5. Do one of the following:

a. Know and tell two different processes by which metals are extracted from ores.

Mineral processing, otherwise known as mineral dressing, is the practice of extracting valuable minerals from their ores.

Industrial mineral treatment processes usually combine a number of unit operations in order to liberate and separate minerals by exploiting the differences in physical properties of the different minerals that make up an ore.

Mineral processing involves four general types of operations: comminution or particle size reduction, sizing or separation of particle sizes by screening or classification, concentration by taking advantage of physical and surface chemical properties, and dewatering or solid/liquid separation.

Comminution

Comminution is particle size reduction of materials. Comminution may be carried out on either dry materials or slurries. Crushing and grinding are the two primary comminution processes. Crushing is normally carried out on "run-of-mine" ore, while grinding (normally carried out after crushing) may be conducted on dry or slurried material.

Sizing

Sizing is the general term for separation of particles according to size.

The simplest of sizing processes is screening, or passing the particles to be sized through a screen or number of screens. Screening equipment can include grizzlies, bar screens, and wire mesh screens. Screens can be static (typically the case for very coarse material), or they can incorporate mechanisms to shake or vibrate the screen.

Classification refers to sizing operations that exploits the differences in settling velocities exhibited by particles of different size. Classification equipment may include ore sorters, gas cyclones, hydrocyclones, rake classifiers, rotating trommels, or fluidized classifers. When the feed material contains particles of different densities as well as particles of different size, a degree of concentration takes place during classification because settling velocities are also dependent on particle density.

Froth flotation

Froth flotation is achieved when particles are separated based on their surface potential. Hydrophobic particles are recovered to the froth, whereas hydrophilic particles are discharged with the tailings stream. Some mineral particles are naturally hydrophobic, whereas others require specific reagent additions to change their surface potentials. Oxide ores, such as spodumene and tantalite can be treated using oxalic acid based collectors. Sulfide ores can be recovered using xanthate or dithiophosphate type collectors.

Gravity concentration

Particles can be classified based on their specific gravity. Gravity concentration processes include:

• Heavy media or dense media separation
• Shaking tables, such as the wilfely table
• Spirals
• Centrifugal bowl concentrators
• Jig concentrators are continuous processing gravity concentration devices.
• Multi gravity separators
• Knelson concentrators

Electrostatic separation

Non-conducting particles maintain an electrostatic charge induced electrically, and so remain pinned to a charged drum. Conducting particles do not maintain the electrostatic charge and so fall off the drum, thus minerals such as ilmenite and rutile can be separated.

Magnetic separation

Minerals such as magnetite and pyrrhotite are naturally magnetic, and so can be separated from non-magnetic particles using strong magnets.

b. Know eight minerals and tell how each is used.

1. Diamonds, in addition to their use as a gemstone, have many industrial uses. Because diamond is the hardest mineral known, it is unsurpassed as a cutting implement. They are also used as abrasives.
2. Copper is a good conductor of electricity, and as such, it is commonly used in household wiring.
3. Silicon can be made to conduct or resist electrical current, and because of this property, it is called a semiconductor. Semiconductors are the foundation of the electronics industry.
4. Talc is the first mineral on Moh's scale of hardness. It is ground into a fine dust and used as baby powder.
5. Graphite is a form of pure carbon. It is mixed with clay to make pencil leads. It is also used in powdered form as a lubricant.
6. Quartz crystals have piezoelectric properties, that is they generate an electric current upon the application of mechanical stress. This electrical current varies at a highly regular rate, making quartz the basis of electrical circuits known as oscillators. Because their oscillation frequency is so stable, quartz crystals are used in clocks and watches.
7. Ruby is another gemstone with industrial uses. It is commonly used in lasers.
8. Halite is the mineral form of sodium chloride, better known as table salt. It is used not only for flavoring foods, but in lowering the melting temperature of water to cause ice to melt from roadways and sidewalks.
9. Fluorite is used instead of glass in some high performance telescopes and camera lens elements. It is also used as a flux to lower the melting point of raw materials in steel production to aid the removal of impurities.

7. What four metals are frequently found in native or free form?

A native metal is any of twenty-one metals that can be found freely in nature. These metals include cadmium, chromium, indium, iron, nickel, tellurium, tin, titanium, and zinc, as well as two groups of metals, the gold group, and the platinum group. The gold group consists of gold, aluminum, copper, lead, mercury, and silver. The platinum group consists of platinum, iridium, osmium, palladium, rhodium, and ruthenium.